Three Primaries, the 12-Position Colour Wheel and a Mixing Chart
Every colour on a beginner's palette can be traced back to red, yellow and blue. Mix two primaries and you get a secondary: yellow and blue make green, red and yellow make orange, red and blue make purple. Mix a primary with the secondary beside it and you get a tertiary, such as yellow-green or red-violet. Those twelve positions form the standard colour wheel, and laid out in a circle they let a learner see how colours relate without memorising anything.
Two relationships come up constantly at the easel. Complementary colours sit opposite each other on the wheel: blue and orange, red and green, yellow and violet. A touch of the complement quietens a colour in a gentler way than black does. Analogous colours sit side by side, and a painting built on three analogous hues usually feels calm and unified.
The single most useful exercise in the early weeks is a mixing chart of your own. Draw a grid of small squares, write a colour name at the head of each row and column, and fill each square with the mix of the two. An extra row with white added in steps shows how each mix shifts in tone. Pin the chart near the table and check it whenever a colour refuses to appear. A good sign the skill is forming: you can guess which two colours to combine before trying them.
A mixing chart you painted yourself sticks in the memory, because every square on it was once stirred on your palette.